Infrared Spectrum of Solid Hydrogen Disulphide
نویسندگان
چکیده
منابع مشابه
Infrared spectrum of the 2-chloroethyl radical in solid para-hydrogen.
The addition reaction of chlorine with ethylene (C(2)H(4)) is expected to proceed via a free radical intermediate, the 2-chloroethyl radical, however, this intermediate has not been previously observed spectroscopically. Irradiation at 365 nm of a co-deposited mixture of Cl(2), C(2)H(4), and p-H(2) at 3.2 K produces a series of new lines in the infrared spectrum. A strong line at 664.0 cm(-1) a...
متن کاملInduced infrared absorption of molecular hydrogen in solid C
We report on the observation of induced infrared absorption in a molecular species trapped within a C60 lattice. Infrared spectra for interstitial H2 show distinct rotational and translational side-bands superimposed on the H2’s highly redshifted (54 cm ) fundamental vibrational mode. Data indicate that the hydrogen is rotating almost completely freely while at the same time undergoing localize...
متن کاملInfrared spectrum of formamide in the solid phase.
Infrared spectra of solid formamide are reported as a function of temperature. Solid formamide samples were prepared at 30 K and then annealed to higher temperatures (300 K) with infrared transmission spectra being recorded over the entire temperature range. The NH(2) vibrations of the formamide molecule were found to be particularly very sensitive to temperature change. The IR spectra revealed...
متن کاملThe infrared spectrum of HOOH+ trapped in solid neon.
When a Ne:H(2)O(2) mixture is codeposited at 4.3 K with a beam of neon atoms that have been excited in a microwave discharge, three new, photosensitive absorptions appear which can be assigned to the three infrared-active vibrational fundamentals of trans-HOOH(+). When the Ne:H(2)O(2) deposition system is pretreated with the vapors of D(2)O, the product absorptions include new peaks which can b...
متن کاملReactions between chlorine atom and acetylene in solid para-hydrogen: infrared spectrum of the 1-chloroethyl radical.
We applied infrared matrix isolation spectroscopy to investigate the reactions between Cl atom and acetylene (C₂H₂) in a para-hydrogen (p-H₂) matrix at 3.2 K; Cl was produced via photodissociation at 365 nm of matrix-isolated Cl₂ in situ. The 1-chloroethyl radical (·CHClCH₃) and chloroethene (C₂H₃Cl) are identified as the main products of the reaction Cl + C₂H₂ in solid p-H₂. IR absorption line...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Communications, Faculty Of Science, University of Ankara Series A1Mathematics and Statistics
سال: 1967
ISSN: 1303-5991
DOI: 10.1501/commua1_0000000213